science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2020

Substance: fenchone					Other Names: 1,3,3-trimethylbicyclo[2.2.1]heptan-2-one

Formula: C10H16O					CAS-No.: 1195-79-5	PubChem: CID 14525

Study: Spectroscopy, UV absorption spectrum

                
Authors: D.P. Singh, N. De Oliveira, G.A. Garcia, A. Vredenborg, I. Powis

Title: An Experimental and Theoretical Investigation of the 3sp(d) Rydberg States of Fenchone by Polarized Laser Resonance-Enhanced-MultiphotonIonization and Fourier Transform VUV Absorption Spectroscopy

Journal/Source: Chem. Phys. Chem., 21 (21) 2468-2483, (2020); https://doi.org/10.1002/cphc.202000365


Data: diagram, table

Energy/Wavelength range: 46000 - 72000 cm-1 (~ 139 - 218 nm)

Resolution: 17.2 cm-1

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration: 0.10 - 0.27 mbar 

Phase: vapor

pH:


Comments: The VUV absorption spectrum of fenchone is re-examined using synchrotron radiation Fourier transform spectrometry, revealing new vibrational structure.