science-softCon uv/vis+ photochemistry database;	www.photochemistry.org; (C) science-softCon 2021

Substance: vinyl radical				Other Names: vinyl 

Formula: C2H3						CAS-No.: 2669-89-8

Study: photochemistry


Authors: J.D. DeSain, L.E. Jusinski, C.A. Taatjes

Title: Ultraviolet photochemistry of trichlorovinylsilane and allyltrichlorosilane: vinyl radical (HCCH2) and allyl radical (H2CCHCH2) production in 193 nm photolysis

Journal/Source: Phys. Chem. Chem. Phys., 8, 2240 - 2248, (2006); DOI: 10.1039/b600755d


Data: 

Energy/Wavelength range: 404 nm

Resolution: 

Temperature: 298 K

Temperature dependence: no

Pressure/Concentration:

Phase: gas

pH:


Comments: The absorption cross sections at 404 nm of vinyl radical ((2.9 ± 0.4) × 10-19 cm2) and allyl radical ((3.6 ± 0.8) × 10-19 cm2) were derived.